Download B Boron Compounds: Boron and Noble Gases, Hydrogen by Lawrence Barton, Thomas Onak, Jürgen Faust, Kurt Niedenzu, PDF

By Lawrence Barton, Thomas Onak, Jürgen Faust, Kurt Niedenzu, R. Bohrer

A vast assurance of boron themes is equipped. Structural elucidations and handy routes to beneficial hydroboration reagents are awarded in addition to boron compounds used for clinical reasons. specified realization is dedicated to theoretical reports and calculations on small boron-hydrogen and boron-noble gasoline species together with molecules like BH, that are relatively favourite matters of theoreticians for trying out quite a few equipment of calculation.

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Extra info for B Boron Compounds: Boron and Noble Gases, Hydrogen

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The corresponding substituted tetrahydroborates are effectively considered as stabilized forms of these boranes. Treatment of the Li[H 2 BR 2 ] or Li[H 3 BR] species with either HCl, (CH 3 lJSiCl, or (CH 3 lJSi0 3 SCH 3 in diethyl ether or n-pentane affords the corresponding alkylborane. In cases where the presence of Lii is tolerable, the use of CH 3 I to Liberate the alkylboranes is very convenient. Some examples of boranes available using this method along with some analytical data are given in Table 2/1.

Helv. Chim. Acta 70 [1987] 1843/54). ; Periasamy, M. (J. Chem. Soc. Chem. Commun. 1987 1857/9). [20] Brown, H. ; Cole, T. E. (Organometallics 4 [1985] 816/21). [21] Keller, P. ; Knapp, K. ; Rund, J. V. (lnorg. Chem. 24 [1985] 2382/3). 4 Carbon Monoxide-Borane, BH 3 -CO, and Its Derivatives For earlier treatment, see "Boron Compounds" 3rd Suppt. Vol. 1, 1987, p. 16, "Boron Compounds" 2nd Suppt. Vol. 1, 1983, pp. 10/12, and "Boron Compounds" 1st Suppt. Vol. 1, 1980, p. 6. BH 3 -CO is a convenient source of BH 3 [1 to 4].

A. 106 [1986] No. 30324). Ip, W. ; Li, W. K. (Croat. Chem. A. 103 [1984] No. 93609). McKee, M. ; Lipscomb, W. N. (lnorg. Chem. 24 [1985] 762/3). Curtiss, L. ; Pople, J. A. (J. Chem. Phys. 89 [1988] 614/5). ; Mayhew, C. ; Berkowitz, J. (J. Chem. Phys. 88 [1988] 5580/93). Curtiss, L. ; Pople, J. A. (J. Phys. Chem. 92 [1988] 894/9). Cullen, J. ; Lipscomb, W. ; Zerner, M. C. (Chem. Phys. Letters 125 [1986] 313/8). Chesnut, D. 8. (Chem. Phys. 110 [1986] 415/20). Stanton, J. ; Lipscomb, W. ; Bartlett, R.

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