Download Bioinorganic Vanadium Chemistry (Inorganic Chemistry: A by Dieter Rehder PDF

By Dieter Rehder

Cotton S. / Коттон С.
Henderson W. / Хендерсон У.
Komiya S. / Комия С.
Lawrence G.A. / Лоренц Дж.А.
Muller U. / Мюллер У.
Rehder D. / Редер Д.
Описание:
Список книг: Amouri, H. / Амури, Х. - Chirality in Transition steel Chemistry. Molecules, Supramolecular Assemblies and fabrics (Inorganic Chemistry - A Textbook sequence) / Хиральность в химии переходных металлов. Молекулы, супрамолекулярные ансамбли и материалы (Неорганическая химия: серия учебников Wiley)
Cotton S. / Коттон С. - Lanthanide and Actinide Chemistry (Inorganic Chemistry - A Textbook sequence) / Химия лантаноидов и актиноидов (Неорганическая химия: серия учебников Wiley)
Henderson W. / Хендерсон У. - Mass Spectrometry of Inorganic, Coordination and Organometallic Compounds - Tools-Techniques-Tips (Inorganic Chemistry - A Textbook sequence) / Масс-спектрометрия неорганических, координационных и металлорганических соединений (Неорганическая химия: серия учебников Wiley)
Komiya S. / Комия С. - Synthesis of Organometallic Compounds - a pragmatic consultant (Inorganic Chemistry - A Textbook sequence) / Синтез металлорганических соединений (Неорганическая химия: серия учебников Wiley)
Lawrence G.A. / Лоренц Дж.А. - creation to Coordination Chemistry (Inorganic Chemistry - A Textbook sequence) / Введение в координационную химию (Неорганическая химия: серия учебников Wiley)
Muller U. / Мюллер У. - Inorganic Structural Chemistry (Inorganic Chemistry - A Textbook sequence) / Структурная неорганическая химия (Неорганическая химия: серия учебников Wiley)
Rehder D. / Редер Д. - Bioinorganic Vanadium Chemistry (Inorganic Chemistry - A Textbook sequence) / Бионеорганическая химия ванадия (Неорганическая химия: серия учебников Wiley)

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Sample text

For a right-handed rotation, the descriptor C (clockwise) is employed, and for the lefthanded rotation the descriptor A (anti-clockwise). e. chiral centres or planes, are present in the ligand system, diastereomers of differing physical (and chemical) properties are generated. Typically, this is the case if amino acids are constituents of ligand systems. 26. 25 Chiral vanadium centres in 5–6-coordinated vanadium complexes with chelating structures (right) and at least four (including the oxo group) different ligands (left).

The complex anion VIII trencam 3− (10) represents a homoleptic catecholatovanadium complex of distorted octahedral geometry. 45 The trigonal twist angle is 41 . The ligand trencam(6−) contains an amine–tris(amide) backbone not directly participating in coordination to vanadium. The VIV and VV complexes 11a and 11b contain o-phenanthroline as an auxiliary ligand.

3). 24 Variations of the cis-dioxovanadium core through (formal) protonation or substitution. e. lacking an inversion centre i and a mirror plane ), the vanadium centre is chiral. For a complex of coordination number 5 or 6, this is the case if there are two chelate-ring structures present, or if there are at least four different functions coordinated to vanadium. 25. For complexes with chelating ligands, the symbols and are used to distinguish between the two enantiomers: when viewed along a threefold (pseudo-) axis, the chelate backbones may form a left-handed ( ) or a right-handed ( ) helix.

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